SWEET ORANGE V3

Hazard statements (CLP)

H317, H332, H400, H410, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Harmful if inhaled. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. May cause an allergic skin reaction

Hazard pictograms

GHS07 GHS09

Signal word

Warning

Contains

Hexyl salicylate; Aldehyde C-16; Hexyl cinnamic aldehyde; Methyl cinnamate; Allyl cyclohexylpropionate; Allyl heptanoate; Allyl amyl glycolate; Allyl caproate; trans-Anethole; Triplal (Vertocitral); Acetate PA; Citronellol Pure; citral; Aldehyde C-12; (R)-p-mentha-1,8- diene; d-limonene

Hazard statements

H317 - May cause an allergic skin reaction. H332 - Harmful if inhaled. H410 - Very toxic to aquatic life with long lasting effects.

Precautionary statements

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water.

Additional information

For professional users only.

2.3 Other hazards

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin sensitisation, Category 1 H317 Hazardous to the aquatic environment – Acute Hazard, H400 Category 1 Hazardous to the aquatic environment – Chronic Hazard, H411 Category 2 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Harmful if inhaled. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. May cause an allergic skin reaction. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS07 GHS09 Signal word (CLP) : Warning Contains : Hexyl salicylate; Aldehyde C-16; Hexyl cinnamic aldehyde; Methyl cinnamate; Allyl cyclohexylpropionate; Allyl heptanoate; Allyl amyl glycolate; Allyl caproate; trans-Anethole; Triplal (Vertocitral); Acetate PA; Citronellol Pure; citral; Aldehyde C-12; (R)-p-mentha-1,8- diene; d-limonene Hazard statements (CLP) : H317 - May cause an allergic skin reaction. H332 - Harmful if inhaled. H410 - Very toxic to aquatic life with long lasting effects. Precautionary statements (CLP) : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. Extra phrases : For professional users only. 2.3. Other hazards Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Bis(2-ethylhexyl) adipate CAS-No.: 103-23-1 15.3 – 30.55 Aquatic Acute 1, H400 substance with national workplace exposure limit(s) EC-No.: 203-090-1 (PL) REACH-no: 01-2119439699- 19 Verdox CAS-No.: 88-41-5 2.1 – 4.2 Aquatic Chronic 2, H411 EC-No.: 201-828-7 REACH-no: 01-2119970713- 33 tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed CAS-No.: 63500-71-0 1 – 4.021 Eye Irrit. 2, H319 isomers (cis and trans) EC-No.: 405-040-6 EC Index-No.: 603-101-00-3 REACH-no: 01-000015458-64 Verdyl propionate CAS-No.: 68912-13-0 1.8 – 3.5 Aquatic Chronic 2, H411 EC-No.: 272-805-7 REACH-no: 01-2119969447- 21 Verdyl acetate CAS-No.: 5413-60-5 1.8 – 3.5 Aquatic Chronic 3, H412 EC-No.: 226-501-6 Aldehyde C-16 CAS-No.: 77-83-8 1.7 – 3.4 Skin Sens. 1B, H317 EC-No.: 201-061-8 Aquatic Chronic 2, H411 REACH-no: 01-2119967770- 28 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Hexyl cinnamic aldehyde CAS-No.: 101-86-0 1.7 – 3.4 Skin Sens. 1, H317 EC-No.: 202-983-3 Aquatic Chronic 2, H411 REACH-no: 01-2119533092- 50 Methyl cinnamate CAS-No.: 103-26-4 1.4 – 2.8 Skin Sens. 1B, H317 EC-No.: 203-093-8 REACH-no: 01-2119979458- 16 Oenanthic ether (Ethyl heptanoate) CAS-No.: 106-30-9 1.2 – 2.3 Flam. Liq. 3, H226 EC-No.: 203-382-9 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 Allyl cyclohexylpropionate CAS-No.: 2705-87-5 1.2 – 2.3 Acute Tox. 4 (Oral), H302 EC-No.: 220-292-5 Acute Tox. 4 (Dermal), H312 Skin Sens. 1, H317 Aquatic Chronic 1, H410 Allyl heptanoate CAS-No.: 142-19-8 1 – 2 Acute Tox. 3 (Oral), H301 EC-No.: 205-527-1 Acute Tox. 3 (Dermal), H311 REACH-no: 01-2119488961- Acute Tox. 3 (Inhalation), H331 23 Aquatic Acute 1, H400 (M=10) Aquatic Chronic 3, H412 Ethyl caproate CAS-No.: 123-66-0 1 – 2 Flam. Liq. 3, H226 EC-No.: 204-640-3 Skin Irrit. 2, H315 isopentyl acetate CAS-No.: 123-92-2 0.9 – 1.8 Flam. Liq. 3, H226 substance with national workplace exposure limit(s) EC-No.: 204-662-3 (AT, BE, BG, CY, DE, DK, EE, ES, FI, FR, GI, GR, EC Index-No.: 607-130-00-2 HR, HU, IE, IT, LT, LU, LV, MT, NL, PL, PT, RO, SE, REACH-no: 01-2119548408- SI, SK, NO, CH, TR); substance with a Community 32 workplace exposure limit Allyl amyl glycolate CAS-No.: 67634-00-8 0.8 – 1.6 Acute Tox. 4 (Oral), H302 EC-No.: 266-803-5 Acute Tox. 2 (Inhalation), H330 Aquatic Chronic 1, H410 Allyl caproate CAS-No.: 123-68-2 0.8 – 1.5 Acute Tox. 3 (Oral), H301 EC-No.: 204-642-4 Acute Tox. 3 (Dermal), H311 REACH-no: 01-2119983573- Acute Tox. 3 (Inhalation), H331 26 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 Ethyl maltol CAS-No.: 4940-11-8 0.8 – 1.5 Acute Tox. 4 (Oral), H302 EC-No.: 225-582-5 trans-Anethole CAS-No.: 4180-23-8 0.7 – 1.4 Skin Sens. 1B, H317 EC-No.: 224-052-0 Benzyl butyrate CAS-No.: 103-37-7 0.6 – 1.2 Acute Tox. 4 (Oral), H302 EC-No.: 203-105-1 Cyclogalbanate (Allyl Cyclohexyl Glycolate) CAS-No.: 68901-15-5 0.5 – 1 Acute Tox. 4 (Oral), H302 EC-No.: 272-657-3 Aquatic Chronic 1, H410 REACH-no: 01-2120770514- 54 Triplal (Vertocitral) CAS-No.: 68039-49-6 0.3 – 0.6945 Skin Irrit. 2, H315 EC-No.: 268-264-1 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Chronic 3, H412 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Acetate PA CAS-No.: 7493-74-5 0.3 – 0.55 Acute Tox. 4 (Oral), H302 EC-No.: 231-335-2 Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Aquatic Acute 1, H400 Citronellol Pure CAS-No.: 106-22-9 0.3 – 0.5 Skin Irrit. 2, H315 EC-No.: 203-375-0 Eye Irrit. 2, H319 REACH-no: 01-2119453995- Skin Sens. 1B, H317 23 Hexyl salicylate CAS-No.: 6259-76-3 0.02 – 0.4 Skin Sens. 1B, H317 EC-No.: 228-408-6 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Chronic 1, H410 benzaldehyde CAS-No.: 100-52-7 0.1 – 0.25 Acute Tox. 4 (Oral), H302 substance with national workplace exposure limit(s) EC-No.: 202-860-4 (BG, FI, HU, LT, LV, PL) EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540- 44 citral CAS-No.: 5392-40-5 0.1 – 0.2 Skin Irrit. 2, H315 substance with national workplace exposure limit(s) EC-No.: 226-394-6 Eye Irrit. 2, H319 (BE, ES, IE, PL, PT) EC Index-No.: 605-019-00-3 Skin Sens. 1, H317 REACH-no: 01-2119462829- 23 benzyl benzoate CAS-No.: 120-51-4 0.1 – 0.132 Acute Tox. 4 (Oral), H302 EC-No.: 204-402-9 Aquatic Acute 1, H400 EC Index-No.: 607-085-00-9 Aquatic Chronic 2, H411 REACH-no: 01-2119976371- 33 Aldehyde C-12 CAS-No.: 112-54-9 0.1 – 0.1 Eye Irrit. 2, H319 EC-No.: 203-983-6 Skin Irrit. 2, H315 Skin Sens. 1B, H317 (R)-p-mentha-1,8-diene; d-limonene CAS-No.: 5989-27-5 0.1 – 0.1 Flam. Liq. 3, H226 substance with national workplace exposure limit(s) EC-No.: 205-341-0 Skin Irrit. 2, H315 (DE, ES, FI, SI, NO, CH) EC Index-No.: 601-096-00-2 Skin Sens. 1B, H317 REACH-no: 01-2119493353- Asp. Tox. 1, H304 35 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 Alcohol C-10 CAS-No.: 112-30-1 0 – 0.0084 Aquatic Chronic 3, H412 substance with national workplace exposure limit(s) EC-No.: 203-956-9 (BG, DE, LT, LV, RO, CH) Aldehyde C-6 CAS-No.: 66-25-1 0 – 0.0021 Flam. Liq. 3, H226 substance with national workplace exposure limit(s) EC-No.: 200-624-5 (FI, PL) Caproic acid CAS-No.: 142-62-1 0 – 0.0001 Eye Dam. 1, H318 substance with national workplace exposure limit(s) EC-No.: 205-550-7 Skin Corr. 1C, H314 (BG, LT, LV) Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a poison center or a doctor if you feel unwell. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. Call a poison center or a doctor if you feel unwell. First-aid measures after skin contact