MAGNOLIA

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Causes skin irritation. Causes serious eye irritation. Toxic to aquatic life with long lasting effects. May cause an allergic skin reaction

Hazard pictograms

GHS07 GHS09

Signal word

Warning

Contains

Hexyl cinnamic aldehyde; Linalool; Linalyl acetate; Cyclamal; Citronellol Pure; Hexyl salicylate; Floralozone; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2- naphthalenyl)ethanone; Triplal (Vertocitral); citral; Helional; (R)-p-mentha-1,8-diene; d- limonene; Pine Needle Oil ; reaction mass of: (1RS, 2RS,3SR, 6RS, 9SR)-9- methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 3RS, 6RS, 8SR)-8- methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 4SR, 6RS, 8SR)-8- methoxytricyclo[5.2.1.0(2,6)]decane-4-carbaldehyde

Hazard statements

H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects.

Precautionary statements

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water.

Additional information

For professional users only.

2.3 Other hazards

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Skin sensitisation, Category 1 H317 Hazardous to the aquatic environment – Chronic Hazard, H411 Category 2 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Causes skin irritation. Causes serious eye irritation. Toxic to aquatic life with long lasting effects. May cause an allergic skin reaction. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS07 GHS09 Signal word (CLP) : Warning Contains : Hexyl cinnamic aldehyde; Linalool; Linalyl acetate; Cyclamal; Citronellol Pure; Hexyl salicylate; Floralozone; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2- naphthalenyl)ethanone; Triplal (Vertocitral); citral; Helional; (R)-p-mentha-1,8-diene; d- limonene; Pine Needle Oil ; reaction mass of: (1RS, 2RS,3SR, 6RS, 9SR)-9- methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 3RS, 6RS, 8SR)-8- methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 4SR, 6RS, 8SR)-8- methoxytricyclo[5.2.1.0(2,6)]decane-4-carbaldehyde Hazard statements (CLP) : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements (CLP) : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. Extra phrases : For professional users only. 2.3. Other hazards Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Hexyl cinnamic aldehyde CAS-No.: 101-86-0 6.8 – 13.62 Skin Sens. 1, H317 EC-No.: 202-983-3 Aquatic Chronic 2, H411 REACH-no: 01-2119533092- 50 Benzyl acetate CAS-No.: 140-11-4 2.6 – 5.11 Aquatic Chronic 3, H412 substance with national workplace exposure limit(s) EC-No.: 205-399-7 (BE, DK, ES, IE, LT, LV, PT, RO) REACH-no: 01-2119638272- 42 Linalool CAS-No.: 78-70-6 2.4 – 4.77 Skin Irrit. 2, H315 EC-No.: 201-134-4 Eye Irrit. 2, H319 EC Index-No.: 603-235-00-2 Skin Sens. 1B, H317 REACH-no: 01-2119474016- 42 Linalyl acetate CAS-No.: 115-95-7 2.4 – 4.77 Skin Irrit. 2, H315 EC-No.: 204-116-4 Eye Irrit. 2, H319 REACH-no: 01-2119454789- Skin Sens. 1, H317 19 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Cyclamal CAS-No.: 103-95-7 2.4 – 4.77 Skin Irrit. 2, H315 EC-No.: 203-161-7 Skin Sens. 1B, H317 REACH-no: 01-2119970582- Aquatic Chronic 2, H411 32 Ethylene brassylate CAS-No.: 105-95-3 2 – 4.09 Aquatic Chronic 2, H411 EC-No.: 203-347-8 REACH-no: 01-2119976314- 33 Dihydromyrcenol CAS-No.: 18479-58-8 1.9 – 3.75 Skin Irrit. 2, H315 EC-No.: 242-362-4 Eye Irrit. 2, H319 REACH-no: 01-2119457274- 37 Citronellol Pure CAS-No.: 106-22-9 1.9 – 3.75 Skin Irrit. 2, H315 EC-No.: 203-375-0 Eye Irrit. 2, H319 REACH-no: 01-2119453995- Skin Sens. 1B, H317 23 Phenylethyl alcohol CAS-No.: 60-12-8 1.6 – 3.15 Acute Tox. 4 (Oral), H302 EC-No.: 200-456-2 Eye Irrit. 2, H319 REACH-no: 01-2119963921- 31 beta-Ionone CAS-No.: 14901-07-6 1.2 – 2.4 Aquatic Chronic 2, H411 EC-No.: 238-969-9 Hexyl salicylate CAS-No.: 6259-76-3 1.1 – 2.2814 Skin Sens. 1B, H317 EC-No.: 228-408-6 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Floralozone CAS-No.: 67634-15-5 1 – 2.04 Aquatic Acute 1, H400 EC-No.: 266-819-2 Aquatic Chronic 2, H411 REACH-no: 01-2120758796- Skin Irrit. 2, H315 34 Skin Sens. 1B, H317 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2- CAS-No.: 54464-57-2 1 – 2.02 Skin Irrit. 2, H315 naphthalenyl)ethanone EC-No.: 259-174-3 Skin Sens. 1, H317 REACH-no: 01-2119489989- Aquatic Chronic 1, H410 04 Citronellyl acetate (mixed Isomers) CAS-No.: 150-84-5 0.9 – 1.7 Aquatic Chronic 2, H411 EC-No.: 205-775-0 Skin Irrit. 2, H315 Triplal (Vertocitral) CAS-No.: 68039-49-6 0.4 – 0.7269 Skin Irrit. 2, H315 EC-No.: 268-264-1 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Chronic 3, H412 citral CAS-No.: 5392-40-5 0.3 – 0.68 Skin Irrit. 2, H315 substance with national workplace exposure limit(s) EC-No.: 226-394-6 Eye Irrit. 2, H319 (BE, ES, IE, PL, PT) EC Index-No.: 605-019-00-3 Skin Sens. 1, H317 REACH-no: 01-2119462829- 23 isopentyl acetate CAS-No.: 123-92-2 0.2 – 0.34 Flam. Liq. 3, H226 substance with national workplace exposure limit(s) EC-No.: 204-662-3 (AT, BE, BG, CY, DE, DK, EE, ES, FI, FR, GI, GR, EC Index-No.: 607-130-00-2 HR, HU, IE, IT, LT, LU, LV, MT, NL, PL, PT, RO, SE, REACH-no: 01-2119548408- SI, SK, NO, CH, TR); substance with a Community 32 workplace exposure limit Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Helional CAS-No.: 1205-17-0 0.2 – 0.34 Skin Sens. 1B, H317 EC-No.: 214-881-6 Repr. 2, H361 REACH-no: 01-2120740119- Aquatic Chronic 2, H411 58 (R)-p-mentha-1,8-diene; d-limonene CAS-No.: 5989-27-5 0.2 – 0.32 Flam. Liq. 3, H226 substance with national workplace exposure limit(s) EC-No.: 205-341-0 Skin Irrit. 2, H315 (DE, ES, FI, SI, NO, CH) EC Index-No.: 601-096-00-2 Skin Sens. 1B, H317 REACH-no: 01-2119493353- Asp. Tox. 1, H304 35 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 Pine Needle Oil CAS-No.: 8002-09-3 0.1 – 0.27 Skin Irrit. 2, H315 EC-No.: 306-895-7 Eye Irrit. 2, H319 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 reaction mass of: (1RS, 2RS,3SR, 6RS, 9SR)-9- CAS-No.: 86803-90-9 0.1 – 0.27 Skin Sens. 1, H317 methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; EC-No.: 617-923-5 Aquatic Chronic 2, H411 (1RS, 2RS, 3RS, 6RS, 8SR)-8- EC Index-No.: 605-034-00-5 methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 4SR, 6RS, 8SR)-8- methoxytricyclo[5.2.1.0(2,6)]decane-4-carbaldehyde Alcohol C-10 CAS-No.: 112-30-1 0 – 0.004 Aquatic Chronic 3, H412 substance with national workplace exposure limit(s) EC-No.: 203-956-9 (BG, DE, LT, LV, RO, CH) Aldehyde C-6 CAS-No.: 66-25-1 0 – 0.001 Flam. Liq. 3, H226 substance with national workplace exposure limit(s) EC-No.: 200-624-5 (FI, PL) Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see Get medical advice/attention. on this label). If skin irritation occurs: Get medical advice/attention. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Section 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Hygiene measures : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. Store in a well-ventilated place. Keep cool. Incompatible products : Strong bases. Strong acids.