LIME, BASIL & MANDARIN V2 FRAGRANCE 928158

Hazard statements (CLP)

H315, H317, H319, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects.

Additional information

EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 3-(O&P- ETHYLPHENYL)-2,2-DIMETHYLPROPIONALDEHYDE, ACETYL CEDRENE, ALPHA- PINENES, BETA-CARYOPHYLLENE, BETA-PINENES, CARVONE, CITRAL, CITRAL-ACID ISOMERIZED, CITRONELLOL, EUGENOL, GERANIAL, GERANYL ACETATE, ISOEUGENOL, ISOMENTHONE, L-LIMONENE, L-MENTHANONE, METHYL ATRATATE, NERAL, NERYL ACETATE, PHENYLACETALDEHYDE, TERPINOLENE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 3- Hazard Label: (O&P-ETHYLPHENYL)-2,2- DIMETHYLPROPIONALDEHYDE, ACETYL CEDRENE, ALPHA-PINENES, BETA-CARYOPHYLLENE, BETA- PINENES, CARVONE, CITRAL, CITRAL-ACID ISOMERIZED, CITRONELLOL, EUGENOL, GERANIAL, GERANYL ACETATE, ISOEUGENOL, ISOMENTHONE, L- LIMONENE, L-MENTHANONE, METHYL ATRATATE, NERAL, NERYL ACETATE, PHENYLACETALDEHYDE, TERPINOLENE Hydrocarbon Concentration %: 5.464%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning 8 Hazard statements: H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects. Supplemental EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 3-(O&P- Information: ETHYLPHENYL)-2,2-DIMETHYLPROPIONALDEHYDE, ACETYL CEDRENE, ALPHA- PINENES, BETA-CARYOPHYLLENE, BETA-PINENES, CARVONE, CITRAL, CITRAL-ACID ISOMERIZED, CITRONELLOL, EUGENOL, GERANIAL, GERANYL ACETATE, ISOEUGENOL, ISOMENTHONE, L-LIMONENE, L-MENTHANONE, METHYL ATRATATE, NERAL, NERYL ACETATE, PHENYLACETALDEHYDE, TERPINOLENE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 3- Hazard Label: (O&P-ETHYLPHENYL)-2,2- DIMETHYLPROPIONALDEHYDE, ACETYL CEDRENE, ALPHA-PINENES, BETA-CARYOPHYLLENE, BETA- PINENES, CARVONE, CITRAL, CITRAL-ACID ISOMERIZED, CITRONELLOL, EUGENOL, GERANIAL, GERANYL ACETATE, ISOEUGENOL, ISOMENTHONE, L- LIMONENE, L-MENTHANONE, METHYL ATRATATE, NERAL, NERYL ACETATE, PHENYLACETALDEHYDE, TERPINOLENE Hydrocarbon Concentration %: 5.464% 8 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Specific Conc. Name CAS EC No. % (CLP) 1272/2008 Limits, M-factors and ATEs 2,6-DIMETHYL-7- SCI 2-EDI 2-STO-SE 3 oral: ATE = 3020 18479-58-8 242-362-4 10-<20% OCTEN-2-OL (NE);H315-H319-H336, - mg/kg bw TETRAHYDRO- METHYL- 63500-71-0 405-040-6 01-0000015458-64-xxxx 5-<10% EDI 2;H319,- (METHYLPROPYL)- PYRAN-4-OL LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 5-<10% SCI 2-EDI 2-SS 1B; H315-H317-H319,- FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 5-<10% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- TETRAHYDROLINALO 78-69-3 201-133-9 01-2119454788-21-xxxx 5-<10% SCI 2-EDI 2-SS 1B; OL H315-H317-H319,- DIMETHYL-4- SCI 2-EH C3;H315- ISOHEPTENAL 67674-46-8 266-885-2 01-2120741268-52-xxxx 1-<5% H412,- DIMETHYL ACETAL ALPHA-ISOMETHYL 127-51-5 204-846-3 1-<5% SS 1B-EH C2;H317- IONONE H411,- inhalation: ATE = 1.5 L-MENTHANONE ATI 4-SCI 2-SS 1B; 14073-97-3 mg/l (dusts or mists)- 237-926-1 1-<5% H315-H317-H332,- oral: ATE = 2219 mg/kg bw CITRAL-ACID FL 2-SS 1B-REP 2-EH ISOMERIZED 147060-73-9, 291-768-8 90480-35-6 1-<5% C2;H225-H317-H361- H411,- FL 3-SCI 2-SS 1B-AH BETA-PINENES 127-91-3 204-872-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- 3-(O&P- ETHYLPHENYL)-2,2- 67634-14-4, 266-818-7, SCI 2-SS 1B-EH A1- DIMETHYLPROPIONAL 67634-15-5 266-819-2 01-2120758796-34-xxxx 0.1-<1% EH C2;H315-H317- DEHYDE H400-H411,- FL 3-REP 2-AH 1-EH oral: ATE = 3650 GAMMA-TERPINENE 99-85-4 202-794-6 0.1-<1% C2;H226-H304-H361- H411,- mg/kg bw ACETYL CEDRENE 32388-55-9 251-020-3 0.1-<1% SS 1B-EH A1-EH C1; oral: ATE = 4500 H317-H410,- mg/kg bw dermal: ATE = 3800 CARVONE 6485-40-1 229-352-5 0.1-<1% SS 1B;H317,- mg/kg bw-oral: ATE = 2500 mg/kg bw METHYL ATRATATE 4707-47-5 225-193-0 0.1-<1% SS 1B;H317,- 2,4-DIMETHYL-3- SCI 2-SS 1B-EH C2; oral: ATE = 2330 CYCLOHEXENE 68039-49-6 268-264-1 0.1-<1% H315-H317-H411,- mg/kg bw CARBOXALDEHYDE GERANIAL 141-27-5 205-476-5 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- NERAL 106-26-3 203-379-2 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- 8 inhalation: ATE = 1.5 ISOMENTHONE 491-07-6 207-727-4 0.1-<1% ATI 4-SCI 2-SS 1B; mg/l (dusts or mists)- H315-H317-H332,- oral: ATE = 2219 mg/kg bw CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 0.1-<1% SCI 2-EDI 2-SS 1; H315-H317-H319,- TERPINOLENE 586-62-9 209-578-0 0.1-<1% SS 1B-AH 1-EH A1-EH oral: ATE = 3775 C1;H304-H317-H410,- mg/kg bw P-MENTH-1-EN-8-OL 10482-56-1 233-986-8 0.1-<1% SCI 2-EDI 1;H315- oral: ATE = 4300 (S) H318,- mg/kg bw GERANYL ACETATE 105-87-3 203-341-5 01-2119973480-35-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; H315-H317-H412,- FL 3-ATO 4-SCI 2-SS ALPHA-PINENES 80-56-8 201-291-9 0.1-<1% 1B-AH 1-EH A1-EH oral: ATE = 500 mg/kg C1;H226-H302-H304- bw H315-H317-H410,- FL 3-SCI 2-EDI 2-AH MYRCENE 123-35-3 204-622-5 0.1-<1% 1-EH A1-EH C2;H226- H304-H315-H319- H400-H411,- FL 3-SCI 2-SS 1B-AH L-LIMONENE 5989-54-8 227-815-6 01-2119958629-18-xxxx 0.1-<1% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- BETA- 87-44-5 201-746-1 0.1-<1% SS 1B-AH 1;H304- CARYOPHYLLENE H317,- THYMOL 89-83-8 201-944-8 0.1-<1% ATO 4-SCI 1B-EDI 1; oral: ATE = 980 mg/kg H302-H314,- bw 106-22-9, 203-375-0, 1117-61-9, 214-250-5, dermal: ATE = 2650 CITRONELLOL 26489-01-0, 247-737-6, 01-2119453995-23-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; mg/kg bw-oral: ATE = 6812-78-8, 229-887-4, H315-H317-H319,- 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 NERYL ACETATE 141-12-8 205-459-2 0.1-<1% SS 1B;H317,- EUGENOL 97-53-0 202-589-1 0.1-<1% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw ATO 4-SCI 1B-EDI 1- PHENYLACETALDEHY 122-78-1 DE dermal: ATE = 2500 204-574-5 0.1-<1% SS 1B-EH C3;H302- mg/kg bw-oral: ATE = H314-H317-H412,- 1550 mg/kg bw Skin Sens. 1; H317; C ATO 4-ATD 4-ATI 4- ≥ 0.01%-inhalation: 97-54-1, 202-590-7, SCI 2-EDI 2-SS 1A- ATE = 1.5 mg/l (dusts ISOEUGENOL 5932-68-3, 227-678-2, <0.1% STO-SE 3(RI);H302- 5912-86-7 227-633-7 H312-H315-H317- or mists)-dermal: ATE H319-H332-H335,- = 1912 mg/kg bw-oral: ATE = 1500 mg/kg bw Substances with Community workplace exposure limits: REACH Registration Classification for Specific Conc. Name CAS EC No. % (CLP) 1272/2008 Limits, M-factors and ATEs ALCOHOL FL 2-EDI 2;H225-H319, 64-17-5 200-578-6 0.1-<1% - DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable 8 Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 8 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Ingredient CAS EC Description Value UK Long-term exposure limit (8-hour TWA) 1000 ppm (ppm) ALCOHOL 64-17-5 200-578-6 UK Long-term exposure limit (8-hour TWA) 1920 mg/m³ (mg/m3) UK Long-term exposure limit (8-hour TWA) 5 mg/m³ (mg/m3) DIETHYL PHTHALATE 84-66-2 201-550-6 UK Short-term exposure limit (15-minute) (mg/m3) 10 mg/m³ 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the 8 following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical State/Colour: Clear pale yellow to yellow liquid Odour: Not determined