TETRA METHYL AMMONIUM BROMIDE FOR SYNTHESIS

Hazard statements (CLP)

H301, H312, H315, H319, H335

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

-DSD Regulation EC 1272/2008 (CLP)] Classification of the substance or mixture

Health hazards

Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP STOT SE 3) H335 Acute toxicity, Oral - Category 3 - Danger (CLP Acute Tox. 3) H301 Skin irritation - Category 2 - Warning (CLP Skin Corr. 2) H315 Eye irritation - Category 2A - Warning (CLP Eye Irrit. 2) H319 Acute toxicity, dermal - Category 4 - Warning (CLP Acute Tox. 4) H312

Hazard pictograms

T Toxic

R-phrase(s)

R21 Harmful in contact with skin. R25 Toxic if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin.

S-phrase(s)

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible).

Signal word

Danger

Hazard statements

H301 Toxic if swallowed. H312 Harmful in contact with skin. H319 Causes serious eye irritation. H315 Causes skin irritation. H335 May cause respiratory irritation.

Prevention

P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product.

Response

P301+P310: IF SWALLOWED Immediately call a POISON CENTER or doctor. P302+P352: IF ON SKIN Wash with plenty of soap and water. P332+P313: If skin irritation occurs Get medical advice. P305+P351+P338: IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340: IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P363: Wash contaminated clothing before reuse.

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. • Disposal considerations P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.

2.1 Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45 Classification : T; R25 Xn; R21 Xi; R36/37/38 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP : STOT SE 3) H335 Acute toxicity, Oral - Category 3 - Danger (CLP : Acute Tox. 3) H301 Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315 Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319 Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312