BIOLOGICAL DEFINITION

Hazard statements (CLP)

H226, H304, H315, H317, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16 CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE FLAM. LIQ. 3 – H226 ASP. TOX. 1 - H304 CLASSIFICATION (EU1272/2008) SKIN IRRIT 2 – H315 SKIN SENS. 1 – H317 AQUATIC CHRONIC 1 - H410

2.2 Label elements

GHS07 GHS08 GHS09 GHS02

Signal word

DANGER.

Contains

- H226 FLAMMABLE LIQUID AND VAPOUR. H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.

Hazard statements

H315 CAUSES SKIN IRRITATION. H317 MAY CAUSE AN ALLERGIC SKIN REACTION. H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. P210 KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING. P241 USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHTING EQUIPMENT. P262 DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. P273 AVOID RELEASE TO THE ENVIRONMENT. P280 WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING AND EYE/FACE PROTECTION.

Precautionary statements

P301+310 IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P303+P361+P353 IF ON SKIN (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. P331 DO NOT INDUCE VOMITING. P405 STORE LOCKED UP. P501 DISPOSE OF CONTENTS/CONTAINER TO … SUPPLEMENTARY PRECAUTIONARY STATEMENTS NONE. SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL.

2.3 Other hazards

ADVERSE PHYSIO-CHEMICAL PROPERTIES NO DATA

Potential Acute Health Effects

NO DATA. PBT OR VPVB ACCORDING TO ANNEX XIII OF NO DATA

2.1 Classification of the substance or mixture

CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16. CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE. FLAM. LIQ. 3 – H226 ASP. TOX. 1 - H304 CLASSIFICATION (EU1272/2008) SKIN IRRIT 2 – H315 SKIN SENS. 1 – H317 AQUATIC CHRONIC 1 - H410 2.2 LABEL ELEMENTS LABEL IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008. GHS LABEL GHS07 GHS08 GHS09 GHS02 SIGNAL WORD DANGER. CONTAINS - H226 FLAMMABLE LIQUID AND VAPOUR. H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. HAZARDS STATEMENT H315 CAUSES SKIN IRRITATION. H317 MAY CAUSE AN ALLERGIC SKIN REACTION. H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. P210 KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING. P241 USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHTING EQUIPMENT. P262 DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. P273 AVOID RELEASE TO THE ENVIRONMENT. P280 WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING AND EYE/FACE PROTECTION. PRECAUTIONARY STATEMENTS P301+310 IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P303+P361+P353 IF ON SKIN (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. P331 DO NOT INDUCE VOMITING. P405 STORE LOCKED UP. P501 DISPOSE OF CONTENTS/CONTAINER TO … SUPPLEMENTARY PRECAUTIONARY STATEMENTS NONE. SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL. 2.3 OTHER HAZARDS ADVERSE PHYSIO-CHEMICAL PROPERTIES NO DATA ADVERSE EFFECTS ON HUMAN HEALTH NO DATA. PBT OR VPVB ACCORDING TO ANNEX XIII NO DATA SECTION 3: COMPOSITION OF INGREDIENTS ~74.0% LIMONENE CAS-NO.: 5989-27-5 EC NO.: 227-813-5CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3 – H226, SKIN IRRIT 2 – H315 ASP TOX. 1 – H304, SKIN SENS. 1 – H317 AQUATIC ACUTE 1 – H400, AQUATIC CHRONIC 1 – H410 3.2 MIXTURES ~18.0% Y-TERPINENE CAS-NO 99-85-4, EC 202-794-6 CLASSIFICATION (EC 1272/2008); FLAM. LIQ. 3 – H226, ASP TOX. 1 –H304; ~2.0% ALPHA-PINENE CAS-NO.: 80-56-8 EC NO.: 201-291-9 CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3 - H226, SKIN SENS. 1 - H317, ASP. TOX. 1 - H304, AQUATIC ACUTE 1 - H400, AQUATIC CHRONIC 1 - H410 ~2.0% MYRCENE (7-METHYL-3-METHYLENEOCTA-1,6-DIENE) CAS-NO.: 123-35-3 EC NO.:204-622-5 CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3 - H226, SKIN IRRIT. 2 - H315, EYE IRRIT. 2 - H319, ASP. TOX. 1 - H304 SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL INFORMATION ALWAYS REMOVE CONTAMINATED CLOTHING IMMEDIATELY. GET MEDICAL ATTENTION IMMEDIATELY. REMOVE FROM EXPOSURE SITE TO FRESH AIR, KEEP AT REST, AND OBTAIN MEDICAL INHALATION ATTENTION. INGESTION GET MEDICAL ATTENTION IMMEDIATELY. RINSE MOUTH WITH WATER AND OBTAIN MEDICAL ATTENTION. SKIN CONTACT REMOVE CONTAMINATED CLOTHES. WASH THOROUGHLY WITH SOAP AND WATER. CONTACT PHYSICIAN IF IRRITATION PERSISTS. EYE CONTACT FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN IF SYMPTOMS PERSIST. INHALATION MAY CAUSE COUGHING AND DIFFICULTIES IN BREATHING. 4.2 INGESTION IRRITATING TO THE RESPIRATORY TRACT AND MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM. MOST IMPORTANT SYMPTOMS & EFFECTS (ACUTE & SKIN CONTACT TOXIC IN CONTACT WITH SKIN. DELAYED) EYE CONTACT MAY CAUSE EYE IRRITATION. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION OR NONE EXPECTED, SEE SECTION 4.1 FOR FURTHER INFORMATION. SPECIAL TREATMENT REQUIRED SECTION 5: FIRE FIGHTING MEASURES 5.1 FOAM, CO2, DRY CHEMICAL POWDER. EXTINGUISHING MATERIAL 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR BURNING PRODUCES IRRITATING, TOXIC AND OBNOXIOUS FUMES MIXTURE 5.3 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: ADVICE FOR FIRE-FIGHTERS WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND APPROPRIATE PROTECTIVE CLOTHING. SECTION 6: ACCIDENTAL RELEASE MEASURES ENSURE ADEQUATE VENTILATION OF THE WORKING AREA, EVACUATE PERSONNEL TO SAFE AREA, WEAR SUITABLE PROTECTIVE 6.1 PERSONAL PRECAUTIONS EQUIPMENT. NO SMOKING, SPARKS, FLAMES OR OTHER SOURCES OF IGNITION NEAR SPILLAGE. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. 6.2 DO NOT DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DISPOSE OF IN LINE WITH LOCAL AUTHORITY ENVIRONMENTAL PRECAUTIONS GUIDELINES. 6.3 METHODS & MATERIAL FOR CONTAINMENT AND CLEANING REMOVE IGNITION SOURCES. PROVIDE ADEQUATE VENTILATION. AVOID EXCESSIVE INHALATION OF VAPOURS. CONTAIN UP SPILLAGE IMMEDIATELY BY USE OF SAND OR INERT POWDER. DISPOSE OF ACCORDING TO LOCAL REGULATIONS. 6.4 REFER & CONSIDER SECTION 8. REFERENCES TO OTHER SECTIONS REFER & CONSIDER SECTION 13. SECTION 7: HANDLING & STORAGE HANDLE IN ACCORDANCE WITH GOOD HYGIENE AND SAFETY PRACTICE. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND 7.1 HOT SURFACES. - NO SMOKING. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. USE IN ACCORDANCE WITH GOOD PRECAUTIONS FOR SAFE-HANDLING MANUFACTURING AND INDUSTRIAL HYGIENE PRACTICES. USE IN AREAS WITH ADEQUATE VENTILATION DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. 7.2 KEEP THE PRODUCT CONTAINER TIGHTLY CLOSED, IN A DRY, VENTILATED AREA. KEEP AWAY FROM POTENTIAL SOURCES OF CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES IGNITION AND PROTECTED FROM LIGHT. MAINTAIN LIMITED CONTACT WITH OXYGEN. 7.3 NO DATA. SPECIFIC END USE(S) SECTION 8: EXPOSURE CONTROLS & PERSONAL PROTECTION 8.1 CONTROL PARAMETERS NONE. 8.2 EXPOSURE CONTROLS EYE PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. HAND PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. UNDER NORMAL CONDITIONS OF USE AND WHERE ADEQUATE VENTILATION IS AVAILABLE TO PREVENT BUILD UP OF EXCESSIVE VAPOUR, THIS MATERIAL SHOULD NOT REQUIRE SPECIAL ENGINEERING CONTROLS. HOWEVER, IN CONDITIONS OF HIGH OR PROLONGED USE, OR HIGH TEMPERATURE OR OTHER CONDITIONS WHICH INCREASE EXPOSURE, THE FOLLOWING ENGINEERING RESPIRATORY EQUIPMENT CONTROLS CAN BE USED TO MINIMISE EXPOSURE TO PERSONNEL: A) INCREASE VENTILATION OF THE AREA WITH LOCAL EXHAUST VENTILATION. B) PERSONNEL CAN USE AN APPROVED, APPROPRIATELY FITTED RESPIRATOR WITH ORGANIC VAPOUR CARTRIDGE OR CANISTERS AND PARTICULATE FILTERS. C) USE CLOSED SYSTEMS FOR TRANSFERRING AND PROCESSING THIS MATERIAL. ALSO REFER TO SECTIONS 2 AND 7. HYGIENE MEASURES GOOD PERSONAL HYGIENE PRACTICES ARE ALWAYS ADVISABLE, ESPECIALLY WHEN WORKING WITH CHEMICALS / OILS. ENGINEERING MEASURES NONE. SKIN PROTECTION WEAR PROTECTIVE CLOTHING TO REDUCE THE RISK OF SKIN AND EYE CONTACT. PERSONAL PROTECTION AVOID INHALATION OF THE PRODUCT. AVOID CONTACT WITH SKIN AND EYES. OTHER PROTECTION WEAR SUITABLE PROTECTION TO AVOID CONTACT WITH SKIN AND EYES. DO NOT INHALE VAPOURS. PROCESS CONDITIONS ENSURE AREA IS WELL VENTILATED. AVOID VAPOUR INHALATION. SAFETY SHOWER & EYE BATH. ENVIROMENTAL EXPOSURE CONTROLS AVOID DISCHARGING INTO DRAINAGE WATER. SECTION 9: PHYSICAL & CHEMICAL PROPERTIES 9.1 PHYSICAL & CHEMICAL PROPERTIES APPEARANCE LIQUID COLOUR ORANGE TO DARK YELLOW ODOUR CHARACTERISTIC, CITRUS, MANDARIN RELATIVE DENSITY 0.839 - 0.849 @ 25°C FLASH POINT (°C) 49°C REFRACTIVE INDEX @ 20 °C 1.469 - 1.479 @ 20°C SOLUBILITY IN WATER @ 20 °C INSOLUBLE IN WATER 9.2 OTHER INFORMATION AUTO-IGNITION: 235°C SECTION 10: STABILITY & REACTIVITY 10.1 REACTIVITY NO HAZARDOUS REACTIONS IF STORED AND HANDLED AS PRESCRIBED / INDICATED. 10.2 CHEMICAL STABILITY STABLE UNDER SUGGESTED STORAGE CONDITIONS (<15°C). 10.3 POSSIBILITY OF HAZARDOUS REACTIONS NO. 10.4 CONDITIONS TO AVOID STORAGE AT HIGH TEMPERATURES. DO NOT STORE ABOVE 15°C. 10.5 INCOMPATIBLE MATERIALS STRONG OXIDISNING SUBSTANCES. 10.6 THIS PRODUCT DOES NOT DECOMPOSE UNDER NORMAL CONDITIONS. UNDER FIRE CONDITIONS THE PRODUCT WILL PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS A MIXTURE OF IRRITATING FUMES & SMOKE & CARBON MONOXIDE. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 TOXICOLOGICAL EFFECTS ACUTE TOXICITY LD50: 5 G/KG [SOURCE RIFM]. SKIN IRRITATION HAZARD STATEMENT: H315 CAUSES SKIN IRRITATION. EYE DAMAGE OR IRRITATION NOT CLASSIFIED AS IRRITATING TO THE EYE [SOURCE RIFM]. RESPIRATORY OR SKIN SENSITIVITY NO DATA GERM CELL MUTAGENICITY NO DATA CARCINOGENICITY NOT APPLICABLE. REPRODUCTIVE TOXICITY NOT APPLICABLE. STOT – SINGLE EXPOSURE NOT APPLICABLE. STOT – REPEATED EXPOSURE NOT APPLICABLE. ASPIRATION HAZARD MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS (H304). NO DATA. OTHER INFORMATION SECTION 12: ECOLOGICAL INFORMATION AQUATIC LIFE: HAZARD STATEMENT: H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. 12.1 ALGAE/AQUATIC PLANTS: EC50 65.9 MG/L (48H) CALCULATED VALUE [SOURCE RIFM]. TOXICITY FISH/AQUATIC INVERTEBRATES: NO ADDITIONAL DATA. PNECS: NO ADDITIONAL DATA. 12.2 PERSISTENCE & DEGRADABILITY EXPECTED TO BE READILY BIODEGRADABLE. 12.3 HAZARD STATEMENT: H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. BIO- ACCUMULATIVE POTENTIAL 12.4 NO DATA. MOBILITY IN SOIL 12.5 RESULTS OF PBT & VPVB ASSESSMENT THIS SUBSTANCE IS NOT CLASSIFIED AS: PBT OR VPVB / CMR. 12.6 OTHER ADVERSE EFFECTS DO NOT ALLOW PRODUCT TO ENTER STREAMS, SEWERS OR OTHER WATERWAYS. SECTION 13: DISPOSAL INFORMATION 13.1 ALWAYS RECOVER SPILLED PRODUCT. DISCARD WASTE MATERIAL WITH AUTHORIZED WASTE WASTE TREATMENT METHODS MANAGEMENT SERVICES. ACT IN ACCORDANCE WITH LOCAL & NATIONAL WASTE REGULATIONS. SECTION 14: TRANSPORT INFORMATION 14.1 TRANSPORT INFORMATION ROAD: 1169 UN NUMBER RAIL: 1169 AIR: 1169 14.2 UN SHIPPING NAME EXTRACTS, AROMATIC, LIQUID ADR/RID/ADN CLASS 3 IMDG CLASS 3 ICAO CLASS/DIVISION 3 TRANSPORT LABELS 14.3 TRANSPORT HAZARD CLASS(ES) ADR/RID/ADN PACKING GROUP III 14.4 IMDG PACKING GROUP III PACKING GROUP ICAO PACKING GROUP III ENVIRONMENTALLY HAZARDOUS SUBSTANCE/MARINE POLLUTANT 14.5 ENVIROMENTAL HAZARDS THIS PRODUCT CONTAINS CONSTITUENTS FLAMMABLES & DANGEROUS FOR THE ENVIRONMENT - IN CASE 14.6 SPECIAL PRECAUTIONS FOR USER OF POURING MAKE SURE TO OUT, LABEL NEW PACKAGE ACCORDINGLY, REPRODUCING ORIGINAL LABEL WITH RELEVANT SYMBOLS. 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 & THE IBC TARIFF NUMBER 3301192000. CODE. SECTION 15: REGULATORY INFORMATION 15.1 PRODUCT SPECIFIC SAFETY, HEALTH & ENVIRONMENTAL REGULATIONS & LEGISLATION REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL OF 18TH EU DIRECTIVES DECEMBER 2006. CONCERNING THE REGISTRATION, EVALUATION, AUTHORIZATION & RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION (EEC) NO793/93 & COMMISSION REGULATION (EC) NO1488/94 AS WELL AS COUNCIL DIRECTIVE 76/769/EEC & COMMISSION DIRECTIVE 91/155/ECC, 93/67/ECC, 93/105/EEC & 2000/21/EC (INCLUDING AMENDMENTS). STATUTORY INSTRUMENTS THE CHEMICALS (HAZARD INFORMATION & PACKAGING FOR SUPPLY REGULATIONS 2009 (S.I.2009 NO 716). CLASSIFICATION & LABELLING OF SUBSTANCES & PREPARATIONS DANGEROUS FOR SUPPLY. SAFETY DATA APPROVED CODE OF PRACTICE SHEETS FOR SUBSTANCES & PREPARATIONS. GUIDANCE NOTES WORKPLACE EXPOSURE LIMITS EH40. CHIP FOR EVERYONE HSG 108. 15.2 CHEMICAL SAFETY ASSESSMENT - SECTION 16: OTHER INFORMATION H226 FLAMMABLE LIQUID AND VAPOUR. H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. HAZARD AND/ OR PRECAUTIONARY STATEMENTS IN FULL H315 CAUSES SKIN IRRITATION. H317 MAY CAUSE AN ALLERGIC SKIN REACTION. H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. TRAINING INSTRUCTIONS: REFER TO POSSIBLE HAZARD BEFORE USE OF THIS PRODUCT. ABBREVIATIONS & ACRONYMS: MSDS MATERIAL SAFETY DATA SHEET. INCI INTERNATIONAL NOMENCLATURE OF COSMETIC INGREDIENTS. CAS CHEMICAL ABSTRACT SERVICE. IMDG INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS. ADR ACCORD EUROPEAN SUR LE TRANSPORT DES MERCHANDISES DANGEREUSES PAR ROUTE (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD). RID INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY RAIL. ICAO INTERNATIONAL CIVIL AVIATION ORGANIZATION. ADN INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS. GHS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION & LABELLING OF CHEMICALS. TREM CARD TRANSPORT EMERGENCY CARD. STOT SPECIFIC TARGET ORGAN TOXICITY. DOCUMENTATION REVISION DATE CHANGE DESCRIPTION 10TH APRIL 2018 DATA LAUNCH The attached information is considered to be correct at the time the client received this information. Please be aware that detail can change and we encourage clients to update their records with MADAR regularly. The information is not and should not be considered a guarantee or warranty, or a part of our contractual or other legal obligations. The information is not to be disclosed to others, reproduced or transmitted in whole or in part without permission from MADAR. SPECIFICATION SHEET PRODUCT NAME: MANDARIN (RED), ESSENTIAL OIL ORGANIC PRODUCT INCI: CITRUS NOBILIS PEEL PRODUCT CODE: OCMAND CAS NUMBER: 84929-38-4 EINECS NUMBER: 284-521-0 MANUFACTURING METHOD: EXPRESSED ANALYTICAL DETAILS RANGE APPEARANCE LIQUID COLOUR PALE ORANGE - DARK ORANGE ODOUR CHARACTERISTIC, SPECIFIC GRAVITY @ 20C 0.835 – 0.855 REFRACTIVE INDEX @ 20C 1.465 – 1.485 OPTICAL ROTATION (C) +80.0 TO +105.0 STORAGE CONDITIONS STORE IN A COOL DRY PLACE AWAY FROM HEAT & SUNLIGHT DOCUMENTATION REVIEW DATE: 16th December 2025 The attached information is considered to be correct at the time the client received this information. Please be aware that detail can change and we encourage clients to update their records with MADAR regularly. The information is not and should not be considered a guarantee or warranty, or a part of our contractual or other legal obligations. The information is not to be disclosed to others, reproduced or transmitted in whole or in part without permission from MADAR. Vegetarian & Vegan Suitability Statement PRODUCT NAME: Mandarin (Red), Essential Oil Organic MADAR Corporation Limited can confirm that the above listed product does not contain dairy or any other animal product, by product or derivative and is therefore suitable for vegetarian and vegan use.