KMIR

Mentions de danger (CLP)

H251, H252, H315, H318, H400, H410

Code

Déclarations

H251

Self-heating; may catch fire

2.1. Classification de la substance ou du mélange

Self-heat. 1; H251 - Skin Irrit. 2; H315 - Eye Dam. 1; H318 For the full text of the H-Statements mentioned in this Section, see Section 16. - Aquatic Acute 1; H400 - Aquatic Chronic 1; H410 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2

2.2 éléments détiquette

o Product identifier: KMIR o Product identifier: MK-151+

Pictogrammes de danger

EUX o Signal word: o Contains: Calcium oxide o Signal word: Warning

Mentions de danger

H252: Self-heating in large quantities; may catch fire. Aluminum oxide: Aquatic toxicity is unlikely due to low solubility. Calcium oxide: LC50: 50,6 mg/| Exposure time:96 h Species: Oncorhynchus mykiss (rainbow trout) Test Type: static test Test Method: OECD Test Guideline 203 Potassium oxide: LC50: 917,6 mg/l Exposure time:96 h Species: Labeo rohita Test Type: semi-static test Test Method: OECD Test Guideline 203 - Toxicity to aquatic invertebrates lron(Il,Ioxide: EC50: > 100 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Test Type: static test Test Method: OECD Test Guideline 202 Aluminum oxide: Aquatic toxicity is unlikely due to low solubility. Calcium oxide: EC50: 49,1 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Test Type: static test Test Method: OECD Test Guideline 202 - H410: Very toxic to aquatic life with long lasting effects. o Precautionary statements - P273;: Avoid release to the environment. SAFETY DATA SHEET MK-151+ - P391: Collect spillage. Other hazards No information available.

Remarques

Damaging effect on aquatic ecosystems possible due to change in the pH value. Read-across (Analogy) Potassium oxide: EC50: 630 mg/l Exposure time: 48 h Species: Ceriodaphnia dubia (water flea) Test Type: static test Test Method: OECD Test Guideline 202 Read-across (Analogy) » Chronic toxicity * Toxicity to fish Aluminum oxide: No toxicity at the limit of solubility Potassium oxide: NOEC: > 2.000 mg/l Exposure time: 40 d Species: Heteropneustes fossilis Test Type: flow-through test Test Method: OECD Test Guideline 210 - Toxicity to aquatic invertebrates Aluminum oxide: No toxicity at the limit of solubility Calcium oxide: NOEC: 33,3 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Test Type: static test Test Method: OECD Test Guideline 202 Damaging effect on aquatic ecosystems possible due to change in the pH value. Read-across (Analogy) Potassium oxide: NOEC: 68 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Read-across (Analogy) » Other organisms relevant to the environment * Toxicity to aquatic plants lron(Il,Ioxide: Aquatic toxicity is unlikely due to low solubility. Aluminum oxide: Aquatic toxicity is unlikely due to low solubility. Calcium oxide: EC50: 184,57 mg/l Exposure time:72h Species: Pseudokirchneriella subcapitata (green algae) Test Type: static test Test Method: OECD Test Guideline 201 Read-across (Analogy) NOEC: 48 mg/l Exposure time:72h Species: Pseudokirchneriella subcapitata (green algae) Test Type: static test Test Method: OECD Test Guideline 201 Read-across (Analogy) Potassium oxide: EC50: 1.337 mg/l Exposure time:120h Species: Nitzschia linearis Test Type: static test Test Method: No information available. Read-across (Analogy) 12.2 Persistence and degradability The methods for determining the biological degradability are not applicable to inorganic substances. lron(Il,Ioxide: Calcium oxide: Potassium oxide: 12.3 Bioaccumulative potential lron(Il,Ioxide: Does not significantly accumulate in organisms. Aluminum oxide: Accumulation in aquatic organisms is unlikely. Accumulation in terrestrial organisms is unlikely. Calcium oxide: Does not significantly accumulate in organisms. Potassium oxide: Does not significantly accumulate in organisms. 12.4 Mobility in soil Aluminum oxide: The product is insoluble and sinks in water. 12.5 Results of PBT and vPvB assessment lron(Il,Ioxide: Not applicable Aluminum oxide: Not applicable Calcium oxide: Not applicable Potassium oxide: Not applicable 12.6 Other adverse effects Product: No data available SECTION 13: Disposal considerations 13.1 Waste treatment methods Dispose of as hazardous waste in compliance with local and national regulations. Haldor Topsge A/S takes no responsibility for the classification of used or contaminated material. Can be offered for metal recovery. SECTION 14: Transport information 14.1

Numéro ONU

2881 14.2 Proper shipping name: Metal Catalyst, Dry (Iron) 14.3 Transport hazard class(es) ADR/RID: Class 4.2; Labels 4.2 IMDG: Class 4.2; Labels 4.2 IAT A: Class 4.2; Labels 4.2 49 CFR: Class 4.2; Labels 4.2 14.4 Packing group: Il 145

Danger pour l'environnement

ADR/RID: None IMDG: None IATA: None 49 CFR: None 14.6 Special precautions for user: No special precautions are needed in handling this material. 14.7 Transport in bulk according to Not applicable for product as supplied. Annex Il of MARPOL 73/78 and the IBC Code: Further information for transport ADR/RID: Tunnel restriction code: (D/E) IMDG: EmsS: F-G, S-M IATA: Packing instruction (cargo aircrafît) : 473 Packing instruction (passenger aircrafît) Transport forbidden SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture o The product is classified as dangerous in accordance with Regulation (EC) No. 1272/2008. o Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical safety assessment No information available. MK-151+ SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name: MK-151+ 1.2 Relevant identified uses of the substance or mixture and uses advised against o Identified uses: Methanol catalyst. 1.3 Details of the supplier of the safety data sheet Manufacture Company: Haldor Topsoe A/S Address: Haldor Topsges Allé 1, 2800 Lyngby Denmark Telephone: +45 4527 2000 Telefax: +45 4527 2999 E-mail address: catalyst-sds@topsoe.dk 1.4 Emergency telephone number UK: +44 0844 892 0111 Other: +45 4527 2000 2.1